1. Materials and Equipment

1.1 Key Raw Materials

The epoxy powder coating formulation uses the following:

• Epoxy resin CYD-014 (E-12): Supplied by Baling Petrochemical.

• Dicyandiamide, DDS, PF: Primary curing agents.

• 2-methylimidazole: Curing accelerator.

• Additional additives: GLP503, benzoin, titanium dioxide, etc.

1.2 Equipment

• High-speed pulverizer

• Mini twin-screw extruder

• Vacuum oven

• Gloss meter and impact tester

• DSC and TGA thermal analysis instruments

2. Experimental Procedure

2.1 Coating Preparation

According to the base formulation, materials are weighed, pre-crushed, extruded, cooled, ground, and sieved to create a fine epoxy powder coating.

2.2 Coating Application

Powder coatings were applied using electrostatic spray and baked under specific curing conditions to evaluate coating properties.

3. Results and Discussion

3.1 DSC Analysis of Different Curing Systems

DSC tests under different heating rates determined the theoretical gelation, curing, and end temperatures for each system. Results showed that:

• Dicyandiamide: Highest curing temperature (182°C), energy-intensive.

• DDS/2-methylimidazole: Lowest curing temperature (131°C), but softening point (110°C) is too close, affecting film leveling.

• Ideal range: 140–150°C for optimal curing and leveling.

3.2 Thermal Stability (TGA)

TGA curves indicated that all systems exhibit similar thermal stability. No significant degradation differences were noted across systems.

3.3 Physical Performance

Non-Volatile Content

NV content above 99.6% is ideal. Dicyandiamide and dicyandiamide/2-methylimidazole systems achieved the best results.

Gloss and Impact Resistance

DDS/2-methylimidazole had the lowest gloss due to poor leveling. The dicyandiamide/2-methylimidazole combination showed the best impact resistance, implying a well-crosslinked epoxy powder coating formulation.

3.4 Electrical Properties

Surface resistance tests showed the dicyandiamide system offers superior insulation, crucial for applications in electrical coatings.

3.5 Best Overall Formulation

The epoxy powder coating formulation using E-12 epoxy, dicyandiamide, and 2-methylimidazole cured at 160°C for 15 minutes achieved:

• Gloss ≥ 83

• NV content: 99.75%

• Adhesion ≤ 1

• Impact ≥ 50 cm

• Surface resistance: 1.33 × 10¹² Ω

• 2-month storage stability

Conclusion

The study confirms that curing agents significantly influence the epoxy powder coating formulation in terms of curing temperature, physical strength, and electrical properties. Among the evaluated systems, the dicyandiamide/2-methylimidazole formulation offers the best overall balance for industrial applications requiring efficient, durable, and stable epoxy powder coatings.